POSS Literature References

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Barry, A. J.; Daudt, W. H.; Domicone, J. J.; Gilkey, J. W. Crystalline Organosilsesquioxanes *. J. Am. Chem. Soc. 1955, 77, 4248–4252.
Olsson, K. Improved Preparation of Octakis(Alkylsilsesquioxanes). Arkiv foer Kemi 1958, 13, 367–378.
Vogt, L. H.; Brown, J. F. Crystalline Methylsilsesquioxanes. Inorg. Chem. 1963, 2, 189–192.
Brown, J. F.; Vogt, L. H.; Prescott, P. I. Preparation and Characterization of the Lower Equilibrated Phenylsilsesquioxanes. J. Am. Chem. Soc. 1964, 86, 1120–1125.
Frye, C. L.; Collins, W. T. Oligomeric Silsesquioxanes, (HSiO3/2)n. J. Am. Chem. Soc. 1970, 92, 5586–5588.
Frye, C. L.; Klosowski, J. M. So-Called “Ladder Structure” of Equilibrated Phenylsilsesquioxane. J. Am. Chem. Soc. 1971, 93, 4599–4601.
Voronkov, M. G.; Martynova, T. N.; Mirskov, R. G.; Belyi, V. I. Octavinylsilsesquioxane. Russian Journal of Organic Chemistry 1979, 49, 1522–1525.
Voronkov, M. G.; Lavrent’yev, V. I. Polyhedral Oligosilsesquioxanes and Their Homo Derivatives. In Inorganic Ring Systems; Boschke, F. L., Dewar, M. J. S., Dunitz, J. D., Hafner, K., Heilbronner, E., Itô, S., Lehn, J.-M., Niedenzu, K., Raymond, K. N., Rees, C. W., Schäfer, K., Vögtle, F., Wittig, G., Series Eds.; Springer Berlin Heidelberg: Berlin, Heidelberg, 1982; Vol. 102, pp 199–236.
Feher, F. J. Polyhedral Oligometallasilsesquioxanes (POMSS) as Models for Silica-Supported Transition-Metal Catalysts.  Synthesis and Characterization of (C5Me5)Zr[(Si7O12)(c-C6H11)7]. J. Am. Chem. Soc. 1986, 108, 3850–3852.
Feher, F. J.; Budzichowski, T. A. Syntheses of Highly-Functionalized Polyhedral Oligosilsesquioxanes. Journal of Organometallic Chemistry 1989, 379, 33–40.
Feher, F. J.; Budzichowski, T. A.; Weller, K. J. Polyhedral Aluminosilsesquioxanes: Soluble Organic Analogs of Aluminosilicates. J. Am. Chem. Soc. 1989, 111, 7288–7289.
Feher, F. J.; Newman, D. A.; Walzer, J. F. Silsesquioxanes as Models for Silica Surfaces. J. Am. Chem. Soc. 1989, 111, 1741–1748.
Kovrigin, V. M.; Lavrent’ev, V. I. Chromatographic-Mass-Spectroscopic Study of the Mechanism of Fomation of Pervinyloctasilsesquioxane in Polycondensation of Vinyltrichlorosilane in Butanol. Russian Journal of Organic Chemistry 1989, 59, 377–383.
Laine, R. M.; Rahn, J. A.; Youngdahl, K. A.; Babonneau, F.; Hoppe, M. L.; Zhang, Z. F.; Harrod, J. F. Synthesis and High Temperature Chemistry of Methylsilsesquioxane Polymers Produced by Titanium-Catalyzed Redistribution of Methylhydridooligo- and -Polysiloxanes. Chem. Mater. 1990, 2, 464–472.
Feher, F. J.; Budzichowski, T. A.; Blanski, R. L.; Weller, K. J.; Ziller, J. W. Facile Syntheses of New Incompletely Condensed Polyhedral Oligosilsesquioxanes: [(C-C5H9)7Si7O9(OH)3], [(c-C7H13)7Si7O9(OH)3], and [(c-C7H13)6Si6O7(OH)4]. Organometallics 1991, 10, 2526–2528.
Feher, F. J.; Walzer, J. F. Synthesis and Characterization of Vanadium-Containing Silsesquioxanes. Inorg. Chem. 1991, 30, 1689–1694.
Weidner, R.; Zeller, N.; Deubzer, B.; Frey, V. Organooligosilsesquioxanes. 5047492, 1991.
Feher, F. J.; Blanski, R. L. Olefin Polymerization by Vanadium-Containing Silsesquioxanes: Synthesis of a Dialkyl-Oxo-Vanadium(V) Complex That Initiates Ethylene Polymerization. J. Am. Chem. Soc. 1992, 114, 5886–5887.
Feher, F. J.; Budzichowski, T. A.; Rahimian, K.; Ziller, J. W. Reactions of Incompletely-Condensed Silsesquioxanes with Pentamethylantimony: A New Synthesis of Metallasilsesquioxanes with Important Implications for the Chemistry of Silica Surfaces. J. Am. Chem. Soc. 1992, 114, 3859–3866.
Shea, K. J.; Loy, D. A.; Webster, O. Arylsilsesquioxane Gels and Related Materials. New Hybrids of Organic and Inorganic Networks. J. Am. Chem. Soc. 1992, 114, 6700–6710.
Feher, F. J.; Tajima, T. L. Synthesis of a Molybdenum-Containing Silsesquioxane Which Rapidly Catalyzes the Metathesis of Olefins. J. Am. Chem. Soc. 1994, 116, 2145–2146.
Baney, R. H.; Itoh, Maki.; Sakakibara, Akihito.; Suzuki, Toshio. Silsesquioxanes. Chem. Rev. 1995, 95, 1409–1430.
Dittmar, U.; Hendan, B. J.; Fl, U. Funktionalisierte Octa-(propylsilsesquioxane) (3-XC 3H 6) 8(SisO 12) Modellverbindungen fiir oberfl ichenmodifizierte Kieselgele. Journal of Organometallic Chemistry 1995, 10.

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Feher, F. J.; Weller, K. J.; Schwab, J. J. Reactions of Hydrosilsesquioxanes and Chlorosilsesquioxanes with Phosphoranes. Organometallics 1995, 14, 2009–2017.

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Lichtenhan, J. D.; Otonari, Y. A.; Carr, M. J. Linear Hybrid Polymer Building Blocks: Methacrylate-Functionalized Polyhedral Oligomeric Silsesquioxane Monomers and Polymers. Macromolecules 1995, 28, 8435–8437.

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Haddad, T. S.; Choe, E.; Lichtenhan, J. D. Hybrid Styryl-Based Polyhedral Oligomeric Silsesquioxane (Poss) Polymers. In Symposium V – Better Ceramics Through Chemistry VII; MRS Online Proceedings Library Archive; 1996; Vol. 435, p 25.

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Sellinger, A.; Laine, R. M. Silsesquioxanes as Synthetic Platforms. Thermally Curable and Photocurable Inorganic/Organic Hybrids. Macromolecules 1996, 29, 2327–2330.

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Unno, M.; Alias, S. B.; Saito, H.; Matsumoto, H. Synthesis of Hexasilsesquioxanes Bearing Bulky Substituents: Hexakis((1,1,2-Trimethylpropyl)Silsesquioxane) and Hexakis( Tert -Butylsilsesquioxane). Organometallics 1996, 15, 2413–2414.

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Zhang, C.; Laine, R. M. Silsesquioxanes as Synthetic Platforms. II. Epoxy-Functionalized Inorganic-Organic Hybrid Species. Journal of Organometallic Chemistry 1996, 521, 199–201.

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Bolln, C.; Tsuchida, A.; Frey, H.; Mülhaupt, R. Thermal Properties of the Homologous Series of 8-Fold Alkyl-Substituted Octasilsesquioxanes. Chem. Mater. 1997, 9, 1475–1479.

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Cauzzi, D.; Costa, M.; Gonsalvi, L.; Pellinghelli, M. A.; Predieri, G.; Tiripicchio, A.; Zanoni, R. Anchoring Rhodium(I) on Thiourea-Functionalized Silica Xerogels and Silsesquioxanes Part II. Matrix Effects on the Selectivity in the Hydroformylation of Styrene. Journal of Organometallic Chemistry 1997, 541, 377–389.

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Feher, F. J.; Phillips, S. H.; Ziller, J. W. Facile and Remarkably Selective Substitution Reactions Involving Framework Silicon Atoms in Silsesquioxane Frameworks. J. Am. Chem. Soc. 1997, 119, 3397–3398.

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Feher, F. J.; Phillips, S. H.; Ziller, J. W. Synthesis and Structural Characterization of a Remarkably Stable, Anionic, Incompletely Condensed Silsesquioxane Framework. Chem. Commun. 1997, No. 9, 829–830.

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Feher, F. J.; Soulivong, D.; Lewis, G. T. Facile Framework Cleavage Reactions of a Completely Condensed Silsesquioxane Framework. J. Am. Chem. Soc. 1997, 119, 11323–11324.

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Harrison, P. G.; Hall, C. PREPARATION AND CHARACTERIZATION OF OCTASILSESQUIOXANE CAGE MONOMERS : Main Group Metal Chemistry. 1997, 20, 515–529.

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Rikowski, E.; Marsmann, H. C. Cage-Rearrangement of Silsesquioxanes. Polyhedron 1997, 16, 3357–3361.

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Feher, F. J.; Wyndham, K. D. Amine and Ester-Substituted Silsesquioxanes: Synthesis, Characterization and Use as a Core for Starburst Dendrimers. Chem. Commun. 1998, No. 3, 323–324.

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Feher, F. Practical Methods for Synthesizing Four Incompletely Condensed Silsesquioxanes from a Single R 8 Si 8 O 12 Framework. Chemical Communications 1998, No. 12, 1279–1280.

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Feher, F.; Wyndham, K.; Knauer, D. Synthesis, Characterization and Lectin Binding Study of Carbohydrate Functionalized Silsesquioxanes. Chemical Communications 1998, No. 21, 2393–2394.

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Feher, F.; Wyndham, K.; Scialdone, M. Octafunctionalized Polyhedral Oligosilsesquioxanes as Scaffolds: Synthesis of Peptidyl Silsesquioxanes. Chemical Communications 1998, No. 14, 1469–1470.

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Jaffrès, P.-A.; Morris, R. E. Synthesis of Highly Functionalised Dendrimers Based on Polyhedral Silsesquioxane Cores. Journal of the Chemical Society, Dalton Transactions 1998, 16, 2767–2770.

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Rattay, M.; Fenske, D.; Jutzi, P. Octakis(Tetracarbonylcobaltio)Octasilsesquioxane: Synthesis, Structure, and Reactivity. Organometallics 1998, 17, 2930–2932.

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Schwab, J. J.; Lichtenhan, J. D. Polyhedral Oligomeric Silsesquioxane(POSS)-Based Polymers. Appl. Organometal. Chem. 1998, 12, 707–713.

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Xiang, K.-H.; Pandey, R.; Pernisz, U. C.; Freeman, C. Theoretical Study of Structural and Electronic Properties of H-Silsesquioxanes. J. Phys. Chem. B 1998, 102, 8704–8711.

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Zhang, C.; Babonneau, F.; Bonhomme, C.; Laine, R. M.; Soles, C. L.; Hristov, H. A.; Yee, A. F. Highly Porous Polyhedral Silsesquioxane Polymers. Synthesis and Characterization. J. Am. Chem. Soc. 1998, 120, 8380–8391.

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Auner, N.; Ziemer, B.; Herrschaft, B.; Ziche, W.; John, P.; Weis, J. Structural Studies of Novel Siloxysilsesquioxanes. European Journal of Inorganic Chemistry 1999, 1999, 1087–1094.

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Duchateau, R.; Harmsen, R. J.; Abbenhuis, H. C. L.; van Santen, R. A.; Meetsma, A.; Thiele, S. K.-H.; Kranenburg, M. Modeling Acidic Sites in Zeolites and Aluminosilicates by Aluminosilsesquioxanes. Chem. Eur. J. 1999, 5, 3130–3135.

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Feher, F. J.; Terroba, R.; Ziller, J. W. Base-Catalyzed Cleavage and Homologation of Polyhedral Oligosilsesquioxanes. Chemical Communications 1999, No. 21, 2153–2154.

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Feher, F. J.; Wyndham, K. D.; Soulivong, D.; Nguyen, F. Syntheses of Highly Functionalized Cube-Octameric Polyhedral Oligosilsesquioxanes (R8Si8O12). J. Chem. Soc., Dalton Trans. 1999, No. 9, 1491–1498.

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Gravel, M.-C.; Zhang, C.; Dinderman, M.; Laine, R. M. Octa(3-Chloroammoniumpropyl) Octasilsesquioxane. Appl. Organometal. Chem. 1999, 13, 329–336.

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Loy, D. A.; Carpenter, J. P.; Alam, T. M.; Shaltout, R.; Dorhout, P. K.; Greaves, J.; Small, J. H.; Shea, K. J. Cyclization Phenomena in the Sol−Gel Polymerization of α,ω-Bis(Triethoxysilyl)Alkanes and Incorporation of the Cyclic Structures into Network Silsesquioxane Polymers. Journal of the American Chemical Society 1999, 121, 5413–5425.

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Lücke, S.; Stoppek-Langner, K.; Kuchinke, J.; Krebs, B. Octakis-(Dimethylphosphanoethyl)-Octasilsesquioxane–Synthesis, Characterization and Reactivity. Journal of Organometallic Chemistry 1999, 584, 11–15.

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Mehl, G. H.; Saez, I. M. Polyhedral Liquid Crystal Silsesquioxanes. 1999.

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Ossadnik, C.; Vepřek, S.; Marsmann, H. C.; Rikowski, E. Photolumineszenzeigenschaften von Substituierten Silsesquioxanen Der Zusammensetzung Rn (SiO1. 5) n. In Silicon Chemistry; Springer, 1999; pp 55–68.

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Eisenberg, P.; Erra-Balsells, R.; Ishikawa, Y.; Lucas, J. C.; Mauri, A. N.; Nonami, H.; Riccardi, C. C.; Williams, R. J. J. Cagelike Precursors of High-Molar-Mass Silsesquioxanes Formed by the Hydrolytic Condensation of Trialkoxysilanes. Macromolecules 2000, 33, 1940–1947.

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Elsäßer, R.; Mehl, G. H.; Goodby, J. W.; Photinos, D. J. Nematic Silsesquioxanes—towards Nanocrystals Dispersed in a Nematic Liquid Crystal Matrix. Chemical Communications 2000, No. 10, 851–852.

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Lu, Y.; Fan, H.; Doke, N.; Loy, D. A.; Assink, R. A.; LaVan, D. A.; Brinker, C. J. Evaporation-Induced Self-Assembly of Hybrid Bridged Silsesquioxane Film and Particulate Mesophases with Integral Organic Functionality. J. Am. Chem. Soc. 2000, 122, 5258–5261.

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Pyun, J.; Matyjaszewski, K. The Synthesis of Hybrid Polymers Using Atom Transfer Radical Polymerization:  Homopolymers and Block Copolymers from Polyhedral Oligomeric Silsesquioxane Monomers. Macromolecules 2000, 33, 217–220.

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Unno, M.; Suto, A.; Takada, K.; Matsumoto, H. Synthesis of Ladder and Cage Silsesquioxanes from 1,2,3,4-Tetrahydroxycyclotetrasiloxane. BCSJ 2000, 73, 215–220.

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Zhang, C.; Laine, R. M. Hydrosilylation of Allyl Alcohol with [HSiMe2OSiO1.5]8: Octa(3-Hydroxypropyldimethylsiloxy)Octasilsesquioxane and Its Octamethacrylate Derivative as Potential Precursors to Hybrid Nanocomposites. J. Am. Chem. Soc. 2000, 122, 6979–6988.

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Choi, J.; Harcup, J.; Yee, A. F.; Zhu, Q.; Laine, R. M. Organic/Inorganic Hybrid Composites from Cubic Silsesquioxanes. J. Am. Chem. Soc. 2001, 123, 11420–11430.

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Li, G.; Wang, L.; Ni, H.; Pittman, C. U. Polyhedral Oligomeric Silsesquioxane (POSS) Polymers and Copolymers: A Review. Journal of Inorganic and Organometallic Polymers 2001, 11, 123–154.

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Manson, B. W.; Morrison, J. J.; Coupar, P. I.; Jaffrès, P.-A.; Morris, R. E. Synthesis of Aldehyde Functionalised Polyhedral Oligomeric Silsesquioxanes. J. Chem. Soc., Dalton Trans. 2001, No. 7, 1123–1127.

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Nowotny, M.; Maschmeyer, T.; Johnson, B. F. G.; Lahuerta, P.; Thomas, J. M.; Davies, J. E. Heterogeneous Dinuclear Rhodium(II) Hydroformylation Catalysts-Performance Evaluation and Silsesquioxane-Based Chemical Modeling M.N. Gratefully Acknowledges Two Successive Senior Research Fellowships from Universitat de Valencia and T.U. Delft and Support from the TMR Network. Angew. Chem. Int. Ed. 2001, 40, 955–958.

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Nowotny, M.; Maschmeyer, T.; Johnson, B. F. G.; Lahuerta, P.; Thomas, J. M.; Davies, J. E. Heterogeneous Dinuclear Rhodium(II) Hydroformylation Catalysts—Performance Evaluation and Silsesquioxane-Based Chemical Modeling. Angew. Chem. Int. Ed. 2001, 40, 955–958.

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Skowronska-Ptasinska, M. D.; Duchateau, R.; van Santen, R. A.; Yap, G. P. A. Methyl Aluminosilsesquioxanes, Models for Lewis Acidic Silica-Grafted Methyl Aluminum Species. Organometallics 2001, 20, 3519–3530.

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Tamaki, R.; Tanaka, Y.; Asuncion, M. Z.; Choi, J.; Laine, R. M. Octa(Aminophenyl)Silsesquioxane as a Nanoconstruction Site. J. Am. Chem. Soc. 2001, 123, 12416–12417.

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Wada, K.; Izuhara, D.; Yamada, K.; Shiotsuki, M.; Kondo, T.; Mitsudo, T. Synthesis of Alkenylene-Bridged Macrocyclic Silsesquioxanes by Ruthenium or Rhodium-Catalyzed Ring-Closing Reactions of Bis(Allyldimethylsilyl) Groups. Chemical Communications 2001, No. 18, 1802–1803.

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Cassagneau, T.; Caruso, F. Oligosilsesquioxanes as Versatile Building Blocks for the Preparation of Self-Assembled Thin Films. J. Am. Chem. Soc. 2002, 124, 8172–8180.

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Deng, J.; Polidan, J. T.; Hottle, J. R.; Farmer-Creely, C. E.; Viers, B. D.; Esker, A. R. Polyhedral Oligomeric Silsesquioxanes:  A New Class of Amphiphiles at the Air/Water Interface. J. Am. Chem. Soc. 2002, 124, 15194–15195.

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Dijkstra, T. W.; Duchateau, R.; van Santen, R. A.; Meetsma, A.; Yap, G. P. A. Silsesquioxane Models for Geminal Silica Surface Silanol Sites. A Spectroscopic Investigation of Different Types of Silanols. J. Am. Chem. Soc. 2002, 124, 9856–9864.

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Duchateau, R. Incompletely Condensed Silsesquioxanes:  Versatile Tools in Developing Silica-Supported Olefin Polymerization Catalysts. Chem. Rev. 2002, 102, 3525–3542.

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Franco, R.; Kandalam, A. K.; Pandey, R.; Pernisz, U. C. Theoretical Study of Structural and Electronic Properties of Methyl Silsesquioxanes. J. Phys. Chem. B 2002, 106, 1709–1713.

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Kapoor, M. P.; Sinha, A. K.; Seelan, S.; Inagaki, S.; Tsubota, S.; Yoshida, H.; Haruta, M. Hydrophobicity Induced Vapor-Phase Oxidation of Propene over Gold Supported on Titanium Incorporated Hybrid Mesoporous Silsesquioxane. Chem. Commun. 2002, No. 23, 2902–2903.

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Liu, N.; Yu, K.; Smarsly, B.; Dunphy, D. R.; Jiang, Y.-B.; Brinker, C. J. Self-Directed Assembly of Photoactive Hybrid Silicates Derived from an Azobenzene-Bridged Silsesquioxane. Journal of the American Chemical Society 2002, 124, 14540–14541.

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Neumann, D.; Fisher, M.; Tran, L.; Matisons, J. G. Synthesis and Characterization of an Isocyanate Functionalized Polyhedral Oligosilsesquioxane and the Subsequent Formation of an Organic−Inorganic Hybrid Polyurethane. J. Am. Chem. Soc. 2002, 124, 13998–13999.

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Richter, I.; Burschka, C.; Tacke, R. Octakis[(2,2,6,6-Tetramethylpiperidino)Methyl]Octasilsesquioxane: Synthesis and Crystal Structure Analysis of a New Aminoorganyl-Functionalized Octasilsesquioxane. Journal of Organometallic Chemistry 2002, 646, 200–203.

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Ropartz, L.; F. Foster, D.; E. Morris, R.; Z. Slawin, A. M.; J. Cole-Hamilton, D. Hydrocarbonylation Reactions Using Alkylphosphine-Containing Dendrimers Based on a Polyhedral Oligosilsesquioxane Core. Journal of the Chemical Society, Dalton Transactions 2002, 9, 1997–2008.

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Tejerina, B.; Gordon, M. S. Insertion Mechanism of N2 and O 2 into T n ( n = 8, 10, 12)-Silsesquioxane Framework. J. Phys. Chem. B 2002, 106, 11764–11770.

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Bassindale, A. R.; Liu, Z.; MacKinnon, I. A.; Taylor, P. G.; Yang, Y.; Light, M. E.; Horton, P. N.; Hursthouse, M. B. A Higher Yielding Route for T 8 Silsesquioxane Cages and X-Ray Crystal Structures of Some Novel Spherosilicates. Dalton transactions 2003, No. 14, 2945–2949.

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Bassindale, A. R.; Liu, Z.; MacKinnon, I. A.; Taylor, P. G.; Yang, Y.; Light, M. E.; Horton, P. N.; Hursthouse, M. B. A Higher Yielding Route for T8 Silsesquioxane Cages and X-Ray Crystal Structures of Some Novel Spherosilicates. Dalton Trans. 2003, No. 14, 2945–2949.

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Bassindale, A. R.; MacKinnon, I. A.; Maesano, M. G.; Taylor, P. G. The Preparation of Hexasilsesquioxane (T 6 ) Cages by “Non Aqueous” Hydrolysis of Trichlorosilanes. Chem. Commun. 2003, No. 12, 1382–1383.

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Bassindale, A. R.; Pourny, M.; Taylor, P. G.; Hursthouse, M. B.; Light, M. E. Fluoride-Ion Encapsulation within a Silsesquioxane Cage. Angew. Chem. Int. Ed. 2003, 42, 3488–3490.

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dell’ Erba, I. E.; Fasce, D. P.; Williams, R. J. J.; Erra-Balsells, R.; Fukuyama, Y.; Nonami, H. Poly(Silsesquioxanes) Derived from the Hydrolytic Condensation of Organotrialkoxysilanes Containing Hydroxyl Groups. Journal of Organometallic Chemistry 2003, 686, 42–51.

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Gerritsen, G.; Duchateau, R.; Yap, G. P. A. Boron, Aluminum, and Gallium Silsesquioxane Compounds, Homogeneous Models for Group 13 Element-Containing Silicates and Zeolites. Organometallics 2003, 22, 100–110.

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König, H. J.; Marsmann, H. C.; Letzel, M. C. Thioether Functionalized Octasilsesquioxanes. In Organosilicon Chemistry V; Auner, N., Weis, J., Eds.; Wiley-VCH Verlag GmbH, 2003; pp 425–428.

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Leu, C.-M.; Reddy, G. M.; Wei, K.-H.; Shu, C.-F. Synthesis and Dielectric Properties of Polyimide-Chain-End Tethered Polyhedral Oligomeric Silsesquioxane Nanocomposites. Chem. Mater. 2003, 15, 2261–2265.

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Severn, J. R.; Duchateau, R.; Santen, R. A. van; Ellis, D. D.; Spek, A. L.; Yap, G. P. A. Silsesquioxane-Bonded Zirconocene Complexes; Soluble Models for Silica-Tethered Olefin Polymerization Catalysts. Dalton Trans. 2003, 2293–2302.

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Unno, M.; Imai, Y.; Matsumoto, H. Hexakis(2,4,6-Triisopropylphenylsilsesquioxane). Silicon Chemistry 2003, 2, 175–178.

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Bassindale, A. R.; Chen, H.; Liu, Z.; MacKinnon, I. A.; Parker, D. J.; Taylor, P. G.; Yang, Y.; Light, M. E.; Horton, P. N.; Hursthouse, M. B. A Higher Yielding Route to Octasilsesquioxane Cages Using Tetrabutylammonium Fluoride, Part 2: Further Synthetic Advances, Mechanistic Investigations and X-Ray Crystal Structure Studies into the Factors That Determine Cage Geometry in the Solid State. Journal of Organometallic Chemistry 2004, 689, 3287–3300.

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Bassindale, A. R.; Parker, D. J.; Pourny, M.; Taylor, P. G.; Horton, P. N.; Hursthouse, M. B. Fluoride Ion Entrapment in Octasilsesquioxane Cages as Models for Ion Entrapment in Zeolites. Further Examples, X-Ray Crystal Structure Studies, and Investigations into How and Why They May Be Formed. Organometallics 2004, 23, 4400–4405.

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Duchateau, R.; Dijkstra, T. W.; van Santen, R. A.; Yap, G. P. A. Silsesquioxane Models for Silica Surface Silanol Sites with Adjacent Siloxide Functionalites and Olefin Polymerization Catalysts Thereof. Chem. Eur. J. 2004, 10, 3979–3990.

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Gao, Y.; Eguchi, A.; Kakehi, K.; Lee, Y. C. Efficient Preparation of Glycoclusters from Silsesquioxanes. Org. Lett. 2004, 6, 3457–3460.

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Hanssen, R. W. J. M.; van Santen, R. A.; Abbenhuis, H. C. L. The Dynamic Status Quo of Polyhedral Silsesquioxane Coordination Chemistry. Eur. J. Inorg. Chem. 2004, 2004, 675–683.

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Kopesky, E. T.; Haddad, T. S.; Cohen, R. E.; McKinley, G. H. Thermomechanical Properties of Poly(Methyl Methacrylate)s Containing Tethered and Untethered Polyhedral Oligomeric Silsesquioxanes. Macromolecules 2004, 37, 8992–9004.

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Lin, W.-J.; Chen, W.-C.; Wu, W.-C.; Niu, Y.-H.; Jen, A. K.-Y. Synthesis and Optoelectronic Properties of Starlike Polyfluorenes with a Silsesquioxane Core. Macromolecules 2004, 37, 2335–2341.

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Lorenz, V.; Gießmann, S.; Gun’ko, Y. K.; Fischer, A. K.; Gilje, J. W.; Edelmann, F. T. Fully Metalated Silsesquioxanes: Building Blocks for the Construction of Catalyst Models. Angew. Chem. Int. Ed. 2004, 43, 4603–4606.

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Lorenz, V.; Gießmann, S.; Gun’ko, Y. K.; Fischer, A. K.; Gilje, J. W.; Edelmann, F. T. Fully Metalated Silsesquioxanes: Building Blocks for the Construction of Catalyst Models. Angew. Chem. 2004, 116, 4703–4706.

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Ni, Y.; Zheng, S.; Nie, K. Morphology and Thermal Properties of Inorganic–Organic Hybrids Involving Epoxy Resin and Polyhedral Oligomeric Silsesquioxanes. Polymer 2004, 45, 5557–5568.

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Pescarmona, P. P.; Masters, A. F.; van der Waal, J. C.; Maschmeyer, T. Osmium Silsesquioxane as Model Compound and Homogeneous Catalyst for the Dihydroxylation of Alkenes. J. Mol. Catal. Chem. 2004, 220, 37–42.

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Brick, C. M.; Tamaki, R.; Kim, S.-G.; Asuncion, M. Z.; Roll, M.; Nemoto, T.; Ouchi, Y.; Chujo, Y.; Laine, R. M. Spherical, Polyfunctional Molecules Using Poly(Bromophenylsilsesquioxane)s as Nanoconstruction Sites. Macromolecules 2005, 38, 4655–4660.

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Chou, C.-H.; Hsu, S.-L.; Dinakaran, K.; Chiu, M.-Y.; Wei, K.-H. Synthesis and Characterization of Luminescent Polyfluorenes Incorporating Side-Chain-Tethered Polyhedral Oligomeric Silsesquioxane Units. Macromolecules 2005, 38, 745–751.

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Fina, A.; Tabuani, D.; Frache, A.; Camino, G. Polypropylene–Polyhedral Oligomeric Silsesquioxanes (POSS) Nanocomposites. Polymer 2005, 46, 7855–7866.

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